Yes, the second one sounds better to me too, but I think that’s because mornings is plural. But the subject of the sentence is one… so take the rest out and it becomes
it was one … that confuse the senses
So I suppose that, technically, it should be the first option (confuses) but it just doesn’t sound right.
Yes, it's the second one. Get rid of 'one of' and it will be clear: those brilliant sunny mornings that confuse the senses. It is one of <i>those</i> and those are brilliantly sunny mornings....