but is there anything he can do to stop the rest of them giving what they've got?
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You say it has been split up informally but if it is museum quality stuff they should have it valued in case there are inheritance tax/death duties to pay on it. If, as individuals, they pay tax on the items they have inherited, I can't see that a member of the family would have a case against them. Presumably, there would also be some record kept by the executor(s) as to who recieved what, and the family could use the list to prove it was all done above board and no-one lost out on monetary value alone.
Of course, if the member of the family desputing the gift to the museum is one of the executors; or if the deceased promised the disputed items to him/her and they have proof of that; or if they reject the alternative items given in compensation for their share in the 'family treasure', I can see it could get complicated.
However, aside from all that. It is entirely possible that a member of the family could dispute the gift to the Museum whether they have legal grounds to do so, or not. And it could still wind up being contested in Court - especially if it is a very personal item like jewelery, campaign medals, or letters.
The museum, meanwhile, would be highly unlikely to accept such a gift while there was any query as to the rightful ownership of the items - Museums follow a strict code of practice on such things. (I'll have to Google it).
(Monetary gifts are different. There have been a number of cases of houses left to a few of the big charities, which members of the deceased families have disputed, but the charity has gone ahead and sold them anyway and kept the proceeds).
- Naomi
<Added>I haven't time to read it but Google:
museum acquisitions code of practice
Which threw up, amongst others:
A Code of Practice on Archives for Museums and Galleries in the United Kingdom
Third Edition, 2002
http://www.archivesandmuseums.org.uk/scam/code.pdf